Eco-friendly spectrofluorimetric determination of remdesivir in the presence of its metabolite in human plasma for therapeutic monitoring in COVID-19 patients.

Publication date: Jun 23, 2025

The global outbreak of the novel coronavirus (COVID-19) has highlighted the urgent need for innovative therapeutic solutions. Remdesivir (REM) was the first drug granted approval by the US FDA for treating hospitalized COVID-19 patients. A selective and sensitive derivative spectrofluorimetric method has been developed and validated for the determination of Remdesivir (REM) in presence of its Alkaline-induced degradation product (AKDP), which is also known to be its metabolite (GS-441524). The method utilized the intrinsic fluorescence properties of REM, achieving a linear response within the range of 3. 0-120. 0 ng/mL at 428. 3 nm using first-order derivative. Methodological parameters were optimized to ensure high sensitivity, with detection and quantification limits of 1. 12 and 3. 67 ng/mL, respectively. This approach successfully quantified REM in pure form, intravenous infusions, and spiked human plasma. Recovery rates in plasma were satisfactory at 97. 64 +/- 1. 87, confirming the method’s suitability for therapeutic drug monitoring (TDM) in COVID-19 patients. Additionally, the environmental sustainability of the method was evaluated using GAPI, AGREE, and RGB12 metrics, underscoring its green and eco-friendly characteristics.

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Concepts Keywords
Coronavirus Adenosine
Fda Adenosine
Optimized Adenosine Monophosphate
Rgb12 Adenosine Monophosphate
Alanine
Alanine
Antiviral Agents
Antiviral Agents
Coronavirus Infections
COVID-19
COVID-19
COVID-19 Drug Treatment
Drug Monitoring
Eco-friendly
GS-441524
Humans
Limit of Detection
Pandemics
remdesivir
Remdesivir
SARS-CoV-2
Spectrofluorimetry
Spectrometry, Fluorescence
Stability indicating
Therapeutic drug monitoring

Semantics

Type Source Name
disease MESH COVID-19
disease MESH infection
disease MESH Middle East Respiratory Syndrome
drug DRUGBANK Oxygen
drug DRUGBANK ATP
drug DRUGBANK Coenzyme M
pathway REACTOME Metabolism
disease MESH drug interactions
drug DRUGBANK Aminophylline
disease IDO susceptibility
drug DRUGBANK Ethanol
drug DRUGBANK Propylene glycol
drug DRUGBANK Polyvinyl alcohol
drug DRUGBANK Sodium hydroxide
drug DRUGBANK Water
drug DRUGBANK Ammonia
drug DRUGBANK Sodium lauryl sulfate
disease IDO quality
drug DRUGBANK Isoxaflutole
disease IDO process
disease IDO reagent
disease IDO assay
disease MESH acute respiratory distress syndrome
disease MESH death
disease MESH pneumonia
disease MESH viral diseases
drug DRUGBANK Bisoprolol
drug DRUGBANK Perindopril
drug DRUGBANK Perampanel
drug DRUGBANK Methacholine
drug DRUGBANK Hydrochlorothiazide
drug DRUGBANK Azilsartan medoxomil
drug DRUGBANK Chlorthalidone
drug DRUGBANK Carbamazepine
drug DRUGBANK Acetaminophen
drug DRUGBANK Ibuprofen
drug DRUGBANK Chlorzoxazone
drug DRUGBANK Amlodipine
drug DRUGBANK Atorvastatin
drug DRUGBANK Aluminium
drug DRUGBANK Alpha-1-proteinase inhibitor
disease IDO host
drug DRUGBANK Activated charcoal
drug DRUGBANK Favipiravir
drug DRUGBANK Mupirocin
drug DRUGBANK Mometasone furoate
drug DRUGBANK Acalabrutinib
drug DRUGBANK L-Tyrosine
disease MESH l tryptophan
drug DRUGBANK Aniracetam
drug DRUGBANK Moxifloxacin
pathway REACTOME Reproduction
drug DRUGBANK Adenosine
drug DRUGBANK Adenosine phosphate
drug DRUGBANK L-Alanine

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