Orally Bioavailable Dopamine D1/D5 Receptor-Biased Agonists to Study the Role of β-Arrestin in Treatment-Related Dyskinesia in Parkinson’s Disease.

Publication date: Jun 24, 2025

Dopamine replacement therapies for Parkinson’s disease often produce dyskinesias with long-term use. Published studies suggest that introducing β-arrestin signaling might be protective for dyskinesia. We advanced known noncatecholamine D1/D5 receptor G protein-biased agonists and found that removal of oxygen in the linker from published compounds limited β-arrestin recruitment, whereas introduction of nitrogen on the central o-phenyl linker favored β-arrestin recruitment and provided orally bioavailable compounds. Cryogenic electron microscopy suggested key receptor-ligand interactions influencing the different bias behaviors. We discovered compound 24, a D1/D5 receptor agonist with β-arrestin recruitment and properties for use in vivo. We compared 24 with tavapadon, which shows weak efficacy for β-arrestin signaling, in a rat model of Parkinson’s disease with L-DOPA-induced dyskinesias. At particular doses, compound 24 produced efficacy comparable to L-DOPA, but with fewer concomitant dyskinesias. This first in vivo study suggests that β-arrestin may have a positive influence on reducing dyskinesias following acute administration.

Concepts Keywords
Arrestin Agonists
Bioavailable Arrestin
Dyskinesias Biased
Ligand Bioavailable
Parkinson D1
D5
Dopamine
Dyskinesia
Dyskinesias
Linker
Parkinson
Published
Receptor
Recruitment
Signaling

Semantics

Type Source Name
drug DRUGBANK Dopamine
disease MESH Dyskinesia
disease MESH Parkinson’s Disease
drug DRUGBANK Oxygen
drug DRUGBANK Nitrogen
drug DRUGBANK Levodopa

Original Article

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