Metal ions govern coronavirus endoribonuclease activity.

Metal ions govern coronavirus endoribonuclease activity.

Publication date: Jan 14, 2026

Coronavirus nonstructural protein 15 (nsp15) is an endoribonuclease that restricts viral double-stranded RNA (dsRNA) accumulation in the cytosol to evade host immunity. Given the co-localization of nsp15 and replicating viral RNA, the mechanism controlling nsp15 activity is essential, yet poorly understood. Although metal ions are widely used as cofactors for enzymes, their role in nsp15 remains elusive. Here, we show that Co2+ or Ni2+ potently activates, whereas Zn2+ inhibits nsp15 of multiple coronaviruses. In the presence of Co2+, cryo-electron microscopy structures of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) nsp15/dsRNA complexes indicate higher dsRNA-binding affinity. Active-site mutation H249A weakens the effects of Co2+, Ni2+, and Zn2+ on SARS-CoV-2 nsp15. Furthermore, the Co2+- or Ni2+-dependent activation of nsp15 is inhibited upon Zn2+ addition, suggesting competitive regulation. Overall, our work identifies the activator and inhibitor ions of nsp15 and suggests a metal-dependent regulatory mechanism of nsp15 activity.

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Concepts Keywords
Co2 Catalytic Domain
Competitive Cobalt
Coronaviruses Cobalt
Genes Cryoelectron Microscopy
Microscopy Endoribonucleases
Endoribonucleases
Humans
Metals
Metals
Mutation
Nickel
Nickel
Protein Binding
RNA, Double-Stranded
RNA, Double-Stranded
RNA, Viral
RNA, Viral
SARS-CoV-2
Viral Nonstructural Proteins
Viral Nonstructural Proteins
Zinc
Zinc

Semantics

Type Source Name
disease MESH severe acute respiratory syndrome
disease MESH syndrome
drug DRUGBANK Coenzyme M
disease MESH viral infections
pathway KEGG Viral replication
pathway REACTOME Reproduction
drug DRUGBANK Uracil
drug DRUGBANK Propylthiouracil
drug DRUGBANK L-Tryptophan
drug DRUGBANK Serine
drug DRUGBANK L-Phenylalanine
drug DRUGBANK Glutamic Acid
drug DRUGBANK L-Lysine
drug DRUGBANK Kanamycin
drug DRUGBANK Chloramphenicol
drug DRUGBANK Isopropyl beta-D-thiogalactopyranoside
drug DRUGBANK Edetic Acid
drug DRUGBANK Biotin
drug DRUGBANK Glycerin
drug DRUGBANK Imidazole
disease MESH Rad
drug DRUGBANK Sodium lauryl sulfate
disease MESH SDS
disease MESH Lad
drug DRUGBANK Potassium Chloride
disease MESH ARS
disease MESH Image
drug DRUGBANK Sodium carbonate
drug DRUGBANK Ademetionine
drug DRUGBANK Urea
drug DRUGBANK Cefoxitin
drug DRUGBANK L-Valine
disease MESH NoD
disease MESH CIP
drug DRUGBANK Tretamine
drug DRUGBANK Cysteamine
drug DRUGBANK Copper
drug DRUGBANK Medical air
drug DRUGBANK Nitrogen
drug DRUGBANK Titanium
drug DRUGBANK Trestolone
drug DRUGBANK Histidine
drug DRUGBANK Albendazole
disease MESH NTD
drug DRUGBANK Phosphate ion
drug DRUGBANK Uridine
drug DRUGBANK Uridine monophosphate
drug DRUGBANK L-Alanine
disease MESH hepatitis
disease MESH diarrhea
drug DRUGBANK ANX-510
drug DRUGBANK Zinc
drug DRUGBANK Cobalt
disease MESH infection
pathway REACTOME Zinc transporters
pathway KEGG Coronavirus disease
drug DRUGBANK Guanidine
disease MESH kno
disease MESH Plan
disease MESH pneumonia
disease MESH COVID 19
pathway REACTOME Apoptosis
drug DRUGBANK (S)-Des-Me-Ampa
drug DRUGBANK Manganese
disease MESH middle east respiratory syndrome
drug DRUGBANK Tipiracil
pathway REACTOME Metabolism
disease MESH Ito
disease MESH Chai
drug DRUGBANK Ranitidine
disease MESH Dis
disease MESH Death
drug DRUGBANK Deoxy-2-Fluoro-B-D-Cellotrioside
drug DRUGBANK Methionine

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